Precipitators can be improved to meet MATS and MACT - Hot Topic Conclusion Yesterday, October 2

 

The speakers yesterday, Bruce Scherer and Dr. Ralph Altman of Particulate Control Technology, and Michael (Mike) James Widico, Vice-President, Business development, APC at KC Cottrell agreed that even relatively small precipitators can be upgraded to meet the new standards for 0.03 lbs/MMbtu. Specific details about how this could be accomplished were provided.

 

There were a number of interesting discussions on rapper design, SO3 conditioning, and flow. One discussion involved the removal of activated carbon particles. It is becoming apparent that considerable mercury is being emitted in the particulate form. The older precipitators are most likely to be the largest emitters. The magnitude of this problem has been discounted because

 

1.      There is no need to measure particulate mercury.

2.      The opacity and the outlet emission have not changed. Therefore there cannot be any activated carbon escaping.

 

EPA may have missed the boat when it decided to require only measurement of gaseous mercury. However, this does not mean that a utility will not be held accountable for particulate mercury emissions. Furthermore with a little bit of mathematics one sees the fallacy in the opacity change logic.

 

The particulate emissions may be 10 mg/Nm3. This is a very low number. However, the mercury requirement translates to 4 micrograms/Nm3. So a plant emitting 10.004 milligrams of dust of which 4 micrograms is mercury it will be at the limit. If it emits 10.005 milligrams it will be in violation. If gaseous emissions are already 3 micrograms then it it only takes 2 micrograms of particulate mercury to make the difference.

 

The fact that substantial differences between sorbent trap and mercury CEMS measurements are being observed is much more meaningful indication of particulate mercury emissions.

 

Bruce and Ralph teamed to make the following analysis relative to improvements:

 

MACT/MATS Compliance 
Limit of 0.03 lb/MMbtu for filterable particulate
      EPA excluded condensable fraction
ESP performance at these low emissions levels dependent on a number of factors
      ESP Optimization must approach ideal conditions more closely than for previous   requirements
|     Upstream equipment dictates inlet conditions           
      Injected sorbents can have a significant effect
      Observed ESP Performance
Most Effective ESP Upgrades
      Installing high frequency power supplies
      Increasing the degree of electrical sectionalization
      Optimizing the gas flow distribution for an ESP
ESP performance insensitive to plate spacing
        9 inch rebuilds are producing very low emissions
        16 inch rebuilds are producing very low emission
The “size” of an ESP needed to meet the new limit keeps getting smaller
SO3/Sorbent Related Issues
Upstream equipment impacts ash layer resistivity
      SOconcentration a major factor controlling resistivity
      Allowable SO3 “window” dictated by:
                  SCR catalyst’s SO2 oxidation can produce high SO3 levels
                  Hg sorbent (ACI) efficiency begins to drop at about 3 ppm of SO3
                  Depending on moisture, ash type, temperature, 3 ppm of SO3 is close to the minimum required for ash conditioning
                  Accurate SO3 control, probably by sorbents, is imperative
      Sorbents incident on ESP a secondary issue
                  Sorbent particle size generally large, easy to capture
                  ACI injection rates minimal, generally don’t impact ash resistivity, re-entrainment from hoppers can be an issue however
                  Sodium based sorbents appear to enhance ash conductivity
                  Calcium sorbents only an issue if SO3 drops too low
Sectionalization
Good sectionalization is a common characteristic of all small, highly efficient ESPs
                  For any given SCA, increased efficiency is realized by increasing sectionalization
                  This correlation holds for both 60 Hz and HF power supplies
Sectionalizing with respect to gas flow preferred
                  Allows energization to more closely follow grain loading
                  Electrically extends the effective length of the ESP
                  Minimizes rapping losses

Gas Flow Optimization
Non-ideal ESP factors previously tolerated must be optimized
                  Sneakage above & below collecting electrodes, hopper re-entrainment
                  Non-uniform velocity profiles across ICAC plane, should be within 10% RMS
                  Temperature & particulate stratification (mixing)
ESP performance at low emission rates is inherently limited by the worst actor of the above factors

Summary
ESPs significantly smaller than 300 SCA on a 9” center basis have been demonstrating sub-MATS emissions
Keeping ash resistivity in the 109ohm-cm range common to most small, high performers is important
Intermittent energization with HF power supplies is beginning to show promise with   higher resistivity ash

Mike Widico explained that KC Cottrell has supplied more than 4500 units around the world and has developed a number of solutions to make precipitators capable of meeting MATS and MACT.

 

§  Improved gas distribution

§  New Internals –collectors, electrodes

§  Improved Rapping

§  Increased power -more T/R sets, or

§  Hi Frequency TRs & control systems

§  Flue gas conditioning

§  Raise the roof

§  Additional inlet / outlet fields

§  New parallel ESP

§  Full or part baghouse conversion

 

One of the major options is the use of sorbents. A sorbent which minimizes resistivity contributes to high collection efficiency. KC Cottrell conducts laboratory studies of various combinations of coals and sorbents in a dedicated laboratory.  KC Cottrell also has magnetic rapper designs which have considerable advantage over the tumbling hammer. The force for each rapper can be adjusted to optimize the cleaning.

 

Individual presentations follow:

 

Precipitator Improvements Webinar - Hot Topic Hour October 2, 2014

Precipitators can be improved to meet MATS and MACT.

Revision Date:  10/2/2014

Tags:  221112 - Fossil Fuel 化石燃料, KC Cottrell, Particulate Control Technologies, Electrostatic Precipitator, Rapper, Maintenance, SO3 Conditioning, MACT, MATS

 

MACT / MATS Compliance by Bruce Scherer and Dr. Ralph Altman, Particulate Control Technology - Hot Topic Hour October 2, 2014

Relatively small precipitators can be upgraded to meet the new standards for 0.03 lbs/MMBtu. Analysis relative to improvements.

Revision Date:  10/2/2014

Tags:  221112 - Fossil Fuel 化石燃料, Particulate Control Technologies, Electrostatic Precipitator, MACT, MATS, Rapper, SO3 Conditioning, Maintenance


ESP Improvements to meet MATS and MACT Rules by Michael James Widico, KC Cottrell - Hot Topic Hour October 2, 2014

Relatively small precipitators can be upgraded to meet the new standards for 0.03 lbs/MMBtu.

Revision Date:  10/2/2014

Tags:  221112 - Fossil Fuel 化石燃料, KC Cottrell, Electrostatic Precipitator, MATS, SO3 Conditioning, Maintenance, MACT, Rapper