Coronavirus Technology Solutions
October 14, 2020

 

Filter Media Market will be Large but Volatile

Acoustical Wall Coverings with Anti-Microbials Available from National Wall Covering

Effectiveness of Antimicrobials Analyzed by Singapore Researchers

Cummins is in Mask Manufacture for the Long Haul

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Filter Media Market will be Large but Volatile

The segments of the filtration industry which use non-woven and membrane filters were $60 billion in 2019. If the lowest true cost choices relative to the coronavirus are selected the market will grow to $80 billion in 2022. This represents an increase of 33 percent over the 2019 revenues. 

Coronavirus variables have the biggest effect on the mask, local air and HVAC purchases. Given the lowest true cost path the media purchases for masks would be over $5 billion. The media purchases for local air and HVAC would be $4 billion. Media purchases for other filtration applications would be over $21 billion.

The lowest true cost analysis recognizes the fact that most virus transmission is through small aerosols. As a result highly efficient masks and filters represent the lowest true cost.

Media suppliers are investing in production lines which will be depreciated over many years. So the market past 2022 is of high interest. The future markets are dependent upon

·         choice of the lowest true cost program or the choice the U.S. and Brazil have taken

·         the timing and impact of vaccines and therapies

·         the impact of the next pandemic, influenza and air pollution

·         the development of new media with higher performance attributes

·         existing capacity versus demand at any point in time.

The filtration media suppliers are facing the challenge of a very volatile market. The 2021 market could vary from $20 to $35 billion. By 2024 the market could vary from $23 billion to $44 billion.

Media suppliers will be well advised to continually adjust forecasts in each application and geography.  Some applications such as rotating equipment have much more certainty than masks.

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The same media which can be used in masks and HVAC filters has applicability in gas turbine intake filters, dust collectors, and liquid cartridges.

Growth in gas turbine inlet filters and dust collection will be much more predictable than media for fan filter units and local air systems.

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Media efficiencies will change substantially from this 2019 split.

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The COVID impact will likely lessen but air pollution and influenza concerns will insure a continuing market.

 

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The Mcilvaine Company has custom reports on filter media and multi client reports on each filtration application. Details are found at
www.mcilvainecompany.com  Bob McIlvaine can answer any questions at rmcilvaine@mcilvainecompany.com or 847 226 2391.

Acoustical Wall Coverings with Anti-Microbials Available from National Wall Covering

National Wall Covering is a distributor operating in 30 States in the U.S. Standard Repeat Acoustical Wallcoverings are a curated selection of repeat-pattern designs printed via dye-sublimation on Sibilance® High Performance Acoustical Felt.

·         Derived from 100% postindustrial recycled  polyester

·         Provides an acoustically rated noise coefficient (NRC) of .20.

·         Highly resistant to shrinking and stretching.

·         Coated for maximum stain resistance and lightfastness (has a lightfastness rating of 5).

·         Fosshield  Antimicrobial Technology: Silver & copper ions incorporated into the polyester fiber naturally attack microbes.

·         Does not absorb moisture making it a durable and long-lasting solution.

·         Easily installed using traditional wallcovering paste and butt seams leaving no visible overlap.

 

 

Fossheild®, an FDA cleared antimicrobial technology incorporating silver and copper ions into the fiber which naturally attack microbes thus delivering surface protection in addition to odor, mold, and bacteria resistance.  

Fosshield is the technology incorporated into the SpectraShield™ 9500 N95 surgical respirator mask. In the FDA testing, Fosshield began microbe prevention immediately and eliminated 99.99% of certain odor-causing bacteria after one hour of contact with the respirator surface.

This antimicrobial technology is a solution for healthcare, living, and workspaces with the added benefit of noise mitigation and visual beauty. 

“ The fiber technology featured in Fosshield® works against the types of airborne bacteria we are most concerned about. This type of ‘capture and kill’ technology is ideal. It’s the silver bullet against bacteria.”  – Dr. Charles Gerba 

Effectiveness of Antimicrobials Analyzed by Singapore Researchers

The Institute of Materials Research in Singapore has just published an extensive analysis of masks. We have excerpted some relevant paragraphs on antimicrobials.

Apart from natural herbal extracts, metals and their compounds have also been extensively studied for their antimicrobial application. Nanoparticles of metal and their compounds have garnered huge attention as a potent antimicrobial agent due to their high surface-to-volume ratios compared with their bulky counterparts. Though each of them has a different mechanism of biocidal action, a generally proposed mechanism includes the disruption of cell membrane metabolism due to the penetration of nanoparticles and/or release of metal ions and the effect of photocatalytic, as reactive oxygen species (ROS) like hydroxyl (HO·) and superoxide radicals (O2) are generated, which induce oxidative stress to microorganisms and cause the ultimate inactivation.

Nanoparticles of silver (Ag), silver compounds (Ag+), titanium dioxide (TiO2), zinc oxide (ZnO), and aluminum and aluminum oxide (Al2O3) have been incorporated to various filters for antimicrobial properties. A synergistic antimicrobial performance is also revealed via their combination with other biocidal agents, such as carbon nanotubes.

Apart from antimicrobial air filters, multifunctional air filters, which simultaneously remove PM, microorganisms, and volatile organic compounds (VOCs), have drawn increasing research attention recently. The integrated multifunctional air filter provides a promising solution to address the high-pressure drop often caused by multiple filters with different functions used in current air filters. Feng et al. designed and fabricated hierarchical Ag/ZnO nanorod-wrapped PTFE nanofibrous membrane with an excellent dynamic antibacterial property of ~100% against Escherichia coli (E. coli), and a formaldehyde degradation rate of 60%, with slightly increased gas penetration, taking advantages of the antimicrobial properties and photocatalytic abilities of both ZnO and nanosilver.

In another study, Zhao et al. reported a multifunctional Ag@MWCNTs Al2O3 hybrid filter, where Ag@MWCNTs with a hierarchical network-like structure uniformly distributed around the pores of the Al2O3 filter. The antimicrobial functionality of Ag nanoparticles, as well as their catalytic performance for formaldehyde degradation, were greatly enhanced when loaded on high surface area of CNTs. Owing to the synergistic integration, the Ag@MWCNTs/Al2O3 hybrid filter demonstrated excellent antimicrobial rate (>98%) against common indoor microorganisms, outstanding degradation of formaldehyde (99.99% at 55°C, and 82.24% at room temperature), and complete retention for particles with sizes ≤ 0.3 μm with a pressure drop of 35.60% compared with the pristine Al2O3 filter.

Copper nanoparticles are strong microbicides for a broad spectrum of microorganisms. Very recently, they have been demonstrated to be effective against the newly emerged 2019 coronavirus (COVID-19), which is threatening the whole world. Though copper-polymer nanocomposites have been explored for antimicrobial applications, the integration of copper nanoparticles to filters for personal protection or air filtration has not been reported yet. With appropriate technologies to effectively deposit copper nanoparticles onto fibrous filter matrix, more advancement for copper nanoparticles as antimicrobial coating in air filters is expected.

 Metal-Organic Frameworks (MOF) an emerging new class of antimicrobials, are superior compared with metals due to their high surface area, uniform distribution of metal active sites, and adjustable porous structures. There has been rapid progress in recent years on the research of antimicrobial behavior of MOFs, along with the antimicrobial application of MOFs and their composites. The antimicrobial mechanism of MOFs is mainly accredited to the inherent biocidal nature from their metal ions and may also be from the antimicrobial organic ligands.

Ma et al. combined MOFs and cellulose fibre (CF) via simple in situ generation and established multifunctional MOFs@CF air filters. The ZIF-8@CF filter exhibited high filtration efficiency of 98.36% against 0.3 μm particles, high gas adsorption ability, and excellent antibacterial activity against E. coli under a pressure drop of 134 Pa. Very recently, inspired by the extremely tunable photocatalytic properties of MOFs, Li et al. exploited their photocatalytic biocidal activities and developed integrated air filters based on the MOFs. ZIF-8 nanocrystals were integrated to nonwoven fabrics via hot pressing. The established MOFilter achieved 96.8% removal of PM2.5 particles with a low-pressure drop (64 Pa) at a flow rate of 0.7 m s−1 and bactericidal efficiency higher than 99.99% over 30 min against aerosols containing E. coli. The dominant disinfection behavior of ZIF-8 here was ascribed to ROS production from photoelectrons trapped at Zn+ centers within ZIF-8 via ligand to metal charge transfer (LMCT), rather than Zn2+ releasing. This work sheds light on the photocatalytic biocidal action of MOFs and provides valuable insights for their potential antimicrobial applications in air disinfection.

 

Several masks have also integrated more than one class of antimicrobial agents across multiple layers. US patent 7845351 disclosed that treating the outer nonwoven layer with antimicrobial agents comprising polyhexamethylene biguanide, citric acid, and N-alkyl polyglycoside, as well as other known antimicrobial agents, can deactivate 99.9% of treated bacteria (MRSA, vancomycin-resistant E. faecalisM. catarrhalis, and K. pneumoniae), fungus C. albicans, and viruses (rhinovirus 1A, influenza A) within 30 minutes of contact. US patent application US20110114095A1 disclosed the use of AgNP-impregnated activated carbon cloth (ACC) as the filtration layer in a face mask; ACC itself showed antiviral activity (93%) against MS-2 coliphage after 6 h incubation, which was enhanced by impregnation of AgNPs (98%). Incorporation of the AgNPs/ACC into a mask resulted in >99.88% virus filtration while having increased air permeability compared to the FFP3 mask. Some FDA-cleared examples of antimicrobial mask include Filigent's BioFriendTM BiomaskTM , cobranded with Medline Curad® BiomaskTM (ONT and OUK), as well as Innonix's RespoKareTM mask line (OUK child masks), which both use 2 wt% citric acid on the outermost spun-bound PP layer, as well as Cu(II) and Zn(II) (1.6 wt% each) coordinated to sulfonated Rayon in a second layer before the melt-blown PP filter. Both antiviral masks inactivated 99.99% of tested influenza A (H1N1, H2N2, H3N2, H5N1, and H5N9) and B viruses within 5 minutes. Nexera Medical's SpectraShieldTM 9500 masks (ONT) use patented Ag-Cu zeolite (Agion®, Sciessen LLC) in the outer PET fibre layer (Fosshield®, Foss Manufacturing); it kills 99.99% of tested bacteria (S. pyogenes, MRSA, and H. influenzae) and can also inactivate SARS, influenza, and filovirus. It has been tested for continuous use for up to 8 hours.

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7429109/

Cummins is in Mask Manufacture for the  Long Haul

Amy Davis, Vice President of Cummins Filtration, shares an update on the company's progress to provide filter media to mask manufacturers around the globe. 

As the world began to grapple with COVID-19, employees at Cummins were working on innovative solutions to help supply PPE that was in high demand. On April 6, Cummins announced plans to use their filter technology to supply critical materials for N95 respirator masks, an essential piece of personal protective equipment for front-line healthcare workers.

Following the N95 announcement, on April 14, Cummins announced an additional partnership with 3M, which would include the utilization of equipment typically used for producing diesel engine filters to manufacture high-efficiency particulate filters for use in 3M’s powered air purifying respirators (PAPRs).

To date, Cummins has provided more than 14 tons of its filtration media to mask manufacturers across the globe, which has been used to produce more than eight million masks. Amy Davis, Vice President of Cummins Filtration, recently shared an update on the company’s progress to date.

Q: First, can you share more about the Cummins Filtration business and your core products?

DAVIS: Our core expertise is designing, manufacturing and selling air, fuel, hydraulic and lube filtration, as well as chemical technology products for diesel and gas-powered equipment around the world. 

Q: How did Cummins Filtration get involved in supplying media for masks?

DAVIS: The need for masks, especially N95 respirator masks, skyrocketed in March and April in response to the COVID-19 pandemic. We learned that many of the world’s leading mask manufacturers needed the critical materials to assemble masks and were struggling to meet demand. We realized that the NanoNet® and NanoForce® Media technology typically found

in filtration products for diesel engines could also be used in surgical masks and N95 respirator masks worn by healthcare professionals to help stop the spread of COVID-19. Once we made that connection, we began exploring partnerships to apply the filter material to masks. 

Q: How has Cummins been able to partner with 3M in an additional effort to meet the surge in demand for PPE due to the COVID-19 outbreak?

DAVIS: We needed to move fast and saw an opportunity to use our existing workforce at our Neillsville, Wisconsin facility to meet this demand. We acquired, commissioned and tested a new pleater in a matter of weeks and have already produced more than 41,000 filters for 3M’s PAPRs since mid-April. Internally, we talk a lot about employee empowerment and decision making and this project is a testament to our employees’ ability to adapt quickly to fill an important supply void in a totally different market. 

Q: What has the response been like from mask manufacturers?

DAVIS: Demand has been strong – in fact, it’s getting to the point where demand will exceed our capacity. Seeing so many organizations inquire about the media reinforced how critical the need for masks was globally. We’ve talked with Universities, health care systems, other automotive companies and mask manufacturers large and small about our media. To date, we’ve supplied 6 tons of the complete composite multilayer media that can be used in N95 masks, and we’ve shipped 8 tons of a simpler polypropylene media that can be used in surgical masks. 

 

Cummins Filter Media - Covid - By the numbers - 3

Q: Do you plan on selling media for masks long-term, or is this a temporary measure to respond to the COVID-19 pandemic?

DAVIS: We’ve added manufacturing capacity and capability to our plants and plan on continuing to supply media for masks as long as there is demand and a need to protect our communities from COVID-19.