AIR POLLUTION MONITORING


& SAMPLING
NEWSLETTER

 

 

January 2010

No. 363

 

REGULATIONS

 

PA Mercury Reduction Rules Do Not withstand Test

 

Pennsylvania's highest court is upholding a decision to throw out a state rule that required coal-fired power plants to cut mercury emissions beyond federal standards. The rule required an 80 percent reduction by 2010 and a 90 percent reduction by 2015. The state Supreme Court ruled that Commonwealth Court Judge Dan Pellegrini was correct when he called the rule unlawful, invalid and unenforceable. The 2007 rule was challenged by PPL Corp., which owns two coal-fired power plants in Pennsylvania. The administration of Gov. Ed Rendell fought industry resistance for approval of the rule, which made Pennsylvania the first major coal-mining state to regulate mercury. However, a federal judge last year required mercury to be restored to a list of hazardous pollutants that Pennsylvania state law prohibits it from regulating.

 

Minnesota PCA Passes Haze Rules for Northern Parks

 

The Minnesota Pollution Control Agency (PCA) has approved new regulations to curb haze over northern Minnesota despite complaints of federal land managers and environmental groups that the rules do not go far enough. The agency’s board voted 7-1 for the measures, aimed at combating haze over pristine areas like Voyageurs National Park, Isle Royale National Park and the Boundary Waters Canoe Area Wilderness that are protected under federal Clean Air Act rules. The rules may eventually affect coal-burning power plants and taconite plants in Minnesota, as well as pulp and paper mills and other industries that may be required to install new haze-cutting pollution-control technology. PCA officials say the new rules are the first step toward cleaner skies over northern Minnesota, cutting 30,000 tons of the haze-causing emissions annually. The rules must be approved by the federal Environmental Protection Agency, which has ordered that air over national parks and wild lands should be haze-free by 2064.

 

Oklahoma Working on Regional Haze Rules

 

The Oklahoma Dept. of Environmental Quality (DEQ) is on the clock to come up with a proposal to reduce regional haze in federal wildlife areas. DEQ hosted a public hearing to allow comments on the plan, which two of the state’s largest utility companies insist could cost them a lot of money. Oklahoma Gas and Electric Co. (OG&E) was the most vocal critic of the plan which officials said could force the utility company to spend more than $1 billion to install scrubbers to clean emissions at its coal-fired power plants. Instead, OG&E wants DEQ to amend the plan so the company can reduce emissions by switching from coal to natural gas to fuel the majority of its power plants.

 

 INDUSTRY NEWS

 

Great Conference Slated for Shanghai May 5-7

 

How can you select a conference title more appropriate to what we do? It is titled “The 14th Sulfur Dioxide, Nitrogen Oxide, Mercury and Fine Particle Pollution Control Technology & Management International Exchange Conference.” McIlvaine is working with the various Chinese sponsors to make sure that this conference maximizes its title claim. There is no exhibition but for a nominal price there is the opportunity to provide a presentation, so it is a much more cost-effective way to make the needed contacts.

 

McIlvaine will be working to help promote the conference with China, as well as working to assure that high quality relevant papers are provided by international experts. McIlvaine will also attempt to maximize networking at the conference. McIlvaine has an office in Shanghai and already publishes “Chinese Utility Plans” in English and Chinese. If you would like more information on the conference, contact Bob McIlvaine at 847-784-0012 ext. 112 or by email at rmcilvaine@mcilvainecompany.com.

 

Yokogawa to Supply Control System for CC Power Plant in Trinidad and Tobago

 

Yokogawa Electric Corp.’s subsidiary, Yokogawa Deutschland GmbH, has received an order from MAN Ferrostaal Industrial Projects GmbH to supply an automation and control system for the La Brea Combined Cycle (CC) Power Plant that is being built by MAN Ferrostaal Industrial Projects GmbH and Eisenbau Essen GmbH for Trinidad Generation Unlimited (TGU). This 720-MW power plant is being built near La Brea, a town on the south side of Trinidad Island. Scheduled to be completed in July 2011, the plant will meet the country’s rising demand for electricity.

 

This new power plant will have six gas turbines, six exhaust gas heat recovery steam generators, two steam turbines and auxiliary facilities. Yokogawa will provide a range of systems and products including a CENTUM® series integrated production control system to control all of these facilities, the ProSafe®-RS Safety Instrumented System for detecting abnormal conditions and safely initiating emergency shutdowns, the Exaquantum™ Plant Information Management System for recording and retrieving historical data, and the PRM™ integrated device management software package, as well as engineering and commissioning services.

 

Enviro Technology to Supply CEMs for 1875-MW Teeside

 

GDF Suez Energy UK has awarded Enviro Technology a contract to supply five continuous emissions monitoring systems (CEMs) for its 1875-MW Teeside combined cycle power station. Enviro Technology has supplied five OPSIS systems to measure NOx, SO2, CO and O2. Associated reporting and data logging software and products have also been purchased.

 

DECISIVE CLASSIFICATION

 

Decisive Classification of Monitoring Technology is Needed

 

Will Americans be able to speak International English? A U.S. news columnist attended an international conference and was surprised to find that even though the conference was all in English, he and his fellow Americans could not understand the speakers. On the other hand, those people who spoke English as a second language seemed to have no problem. He conjectured that we may reach a point where Americans would be the only ones not understanding International English.

 

His analysis was focused on the pronunciation. But there is a far more serious threat. The definition of English technical words is now being transformed by the Asians. Here is a very obvious example. If you Google the words “Denitration SCR,” you see a display of links to articles in English by Chinese, Korean and Japanese authors. You also see U.S. patent references but all for applications by Asians.

 

We are helping the organizers of the “The 14th Sulfur Dioxide, Nitrogen Oxide, Mercury and Fine Particle Pollution Control Technology Conference” to be held next May in Shanghai. Their website is much better than those for other Chinese conferences in terms of English usage. But they do use “denitration” instead of DeNOx or NOx reduction. The words “denitration” and denitrifcation have been used to describe elimination or reduction of nitrogen compounds. Since DeNOx eliminates oxygen, denitration is theoretically incorrect. But denitration seems to be the word of choice instead of DeNOx in Asia. Since definitions are ever changing and validated by usage it will not be long before denitration is equally acceptable.

 

If there is confusion at the highest fluency level, the problem is magnified tremendously as we move down the proficiency scale. Many English versions of conference programs and websites of Asian companies have words, phrases, and whole paragraphs that are either incomprehensible or confusing.

 

As part of its “Free News” site McIlvaine will be tackling this problem with the development of standard terminology in both English and in Chinese. The first step is to establish the standard classification terms in English. Much of this is already started in the five Air Quality Decision trees.

 

“Decisive Classification” is displayed at

http://www.mcilvainecompany.com/Universal_Decision_Tree/subscriber/Tree/Default.htm.

 

The classification system is a foster lineage formed with children from genetic lineages. Here are some foster lineages relevant to monitoring.

 

221112 - Fossil Fuel 化石燃料

Coal-Fired 燃煤

Air Quality 空气质量

CO2 二氧化碳

CO2 Emission Monitoring 二氧化碳排放监测

Protocols 协议

 

Each column is a word or phrase selected from a genetic lineage. CO2 is a child of Air Quality. Its siblings are DeNOx, FGD, Particulate, SO3 and Mercury. This is decisive classification because the division is based on the need for unique technology. Theoretically, FGD which involves SO2 might be the parent of SO3 but since scrubbers do not do a good job of removing SO33 it needs a separate column. 

 

Using the same decisive logic HCl is not listed as a separate technology. The reason is that the FGD scrubber which captures the SO2 will also capture the HCL. The opposite is true in classifying air pollution technologies for waste incinerators. HCL would be the major class and SO2 would be incidental.

 

221112 - Fossil Fuel 化石燃料

Coal-Fired 燃煤

Air Quality 空气质量

CO2 二氧化碳

CO2 Emission Monitoring 二氧化碳排放监测

CO2 Monitors 二氧化碳监测器

 

 

221112 - Fossil Fuel 化石燃料

Coal-Fired 燃煤

Air Quality 空气质量

CO2 二氧化碳

CO2 Regulations 二氧化碳排放规则

 

United States 美国

Federal Regulations 联邦法规

EPA Regulations 环保署法规

 

CO2 Emission Reporting 二氧化碳排放报告

Electric Generating Units 发电机组

 

221112 - Fossil Fuel 化石燃料

Coal-Fired 燃煤

Air Quality 空气质量

CO2

二氧化碳

CO2 Regulations 二氧化碳排放规则

United States 美国

 

Federal Regulations 联邦法规  EPA Regulations 环保署法规

CO2 Emission Reporting 二氧化碳排放报告

Greenhouse Gas Reporting Rule 温室气体报告规则

 

These displays from the McIlvaine CO2 decisions system also illustrate the way Chinese equivalents are displayed.

 

Here are some examples from FGD Decisions system.

 

Electric Utilities - coal-fired boilers – air quality - FGD

 

Optimization & Instrumentation

Gas Monitoring

CEMS

Sources

Beijing Care

Products

 

Electric Utilities - coal-fired boilers – air quality - FGD

 

Level 5

Level 6

Level 7

Level 8

Level 9

Optimization & Instrumentation

Optimization Systems

Sources

ABB

 

Optimization & Instrumentation

Gas Monitoring

CEMS

Sources

ABB

 

Electric Utilities - coal-fired boilers – air quality - FGD

 

Level 6

Level 7

Level 8

Level 9

Optimization & Instrumentation

Optimization Systems

Sources

Emerson

Optimization & Instrumentation

Liquid Process Ins.

Sources

Emerson

 

Electric Utilities - coal-fired boilers – air quality - FGD

 

Level 2

Level 3

Level 4

 Level 5

Procedural

Before Contract

Preliminary Analysis

Who

 Level 6

Level 7

Level 8

 Stack Testing

Sources

Clean Air Engineering

 

 

Electric Utilities - coal-fired boilers – air quality - FGD

 

Level 4

Level 5

Level 6

Level 7

Level 8

Optimization & Instrumentation

Gas Monitoring

CEMS

Sources

Durag

Optimization & Instrumentation

Gas Monitoring

Air Flow Monitors

Sources

Durag

 

The foster family sequence includes links to extensive data at each step along the way.

 

Here is an example from the NOx Decision Tree.

 

Electric Utilities—coal-fired boilers – air quality - DeNOx

 

Components

Gas Monitoring and Analysis

Sources

Sick Maihak

Products

 

NOx Continuing Decision Process For: Products

 

CEM Measurement of NH3 and Low Level NOx. Presented by Dan Kietzer, Sick Maihak. Hot Topic Hour October 22, 2009.

http://www.mcilvainecompany.com/NOx_Decision_Tree/subscriber/Tree/DescriptionTextLinks/Dan Kietzer - Sick Maihak 10-22-09.pdf

 

In-situ - System with Standard Components, presented by Dan Kietzer, Sick Maihak. Hot Topic Hour November 13, 2008.

http://www.mcilvainecompany.com/NOx_Decision_Tree/subscriber/Tree/DescriptionTextLinks/Phillip Zyskowski - Sick Maihak - 11-13-2008 Part 2.pdf

 

Application SCR DeNOx Plant

http://www.mcilvainecompany.com/NOx_Decision_Tree/subscriber/Tree/DescriptionTextLinks/Sick MaihakMcIlvaine 7-12-07 Presentation.htm

 

The final examples are from the Particulate Decision Tree.

 

Electric Utilities—coal-fired boilers – air quality - Particulate

 

Optimization & Instrumentation

Mass Monitoring

Sources

ThermoFisher

Products

 

Particulate Continuing Decision Process For: Products

 

Continuous PM CEMS Update, presented by Jeremy Whorton, ThermoFisher. Hot Topic Hour October 1, 2009.

http://www.mcilvainecompany.com/Particulate_Decision_Tree/subscriber/Tree/DescriptionTextLinks/Jeremy Whorton - ThermoFisher - 10-01-09.pdf

 

Electric Utilities - coal-fired boilers – air quality - mercury

 

Start

Remove

Physical

CEMS

Sources

Shaw

Products

 

Mercury Continuing Decision Process For: Products

 

Managing your HG CEMS Maintenance and Certification. Presented by Terry Marsh, Shaw Environmental Hot Topic Hour March 6, 2008.

http://www.mcilvainecompany.com/MercuryDecision_Tree/subscriber/Tree/DescriptionTextLinks/Terry Marsh, Shaw McIlvaine Presentation March 2008.pdf

 

CMMS and Appendix K - July 12, 2007

http://www.mcilvainecompany.com/MercuryDecision_Tree/subscriber/Tree/DescriptionTextLinks/Shaw Appendix K Hot Topic Pres.htm

 

Hg Monitoring Update - April 12, 2007

http://www.mcilvainecompany.com/MercuryDecision_Tree/subscriber/Tree/DescriptionTextLinks/Hot Topic Hg Presentation April 2007.pdf

 

How Do the Suppliers Classify Their Products?

 

The above examples illustrate how the foster lineages are constructed from genetic lineages. Now let’s look at some of the genetic classification challenges.

 

Source:     Gas Analyzers

Source:     Particulate Analyzers

Source:     Flow and Opacity Monitors

Ambient:    Particulate Analyzers

Ambient:    Gas Analyzers

 

Under source gas analyzers the company lists the following:

 

Thermo Scientific instruments for source emissions monitoring needs.

 

CO Gas Analyzer, Model 48i

Gas filter correlation gas analyzer with enhanced communication capabilities

 

CO2 Gas Analyzers, Model 410i

Optical filter gas analyzer with enhanced communication capabilities for source emissions monitoring

 

Direct Methane, Non-Methane Analyzer, Model 55i

Measurement of direct and non-direct methane utilizing FID technology

 

FTIR Multi-Gas CEMS, Model 70

Continuous monitoring of up to ten gases or more with only one system

 

H2S - SO2 Analyzer, Model 450i

Pulsed fluorescence technology catalytically converts H2S to SO2

 

High Level CO Analyzer, Model 48i-HL

Using gas filter correlation technology, the Model 48i-HL measures the amount of carbon monoxide in the sample.

 

High Level NO-NO2-NOx Analyzer, Model 42i HL

Chemiluminescent gas analyzer with enhanced communication capabilities

 

Hydrogen Chloride Analyzer, Model 15i HCl

New! Utilizing gas filter correlation technology it measures ppm levels of HCl

 

Low Source NO-NO2-NOx Analyzer, Model 42i LS

Low source chemiluminescent gas analyzer w/enhanced communication capabilities

 

Mercury Analyzer, Model 80i

It's time for a new standard in mercury emissions monitoring

 

NDIR Multi-Gas Analyzer, Model 60i

Five gas analyzer utilizing non-dispersive infrared technology

 

NO-NO2-NOx Analyzer, Model 42i

Chemiluminescent gas analyzer with enhanced communication capabilities for ambient air and source emissions monitoring.

 

NOx Only Analyzer, Model 42i-D

Using chemiluminescence technology, the Model 42i-D measures the amount of nitrogen oxides in the air from sub-ppb levels up to 100ppm.

 

SO2 Gas Analyzer, Model 43i

Pulsed fluorescence gas analyzer with enhanced communication capabilities for ambient air and source emissions monitoring.

 

Total Hydrocarbon Gas Analyzer, Model 51i

 

Monitor Labs uses the following classification:

 

Products

·         Continuous Emission Monitoring Systems

 

    o    In situ

·         Flow Monitors

    o    UltraFlow 150

 

·         Gas Monitors

    o    Sensor-e®

 

·         Opacity Monitors

    o    LightHawk®

 

·         Particulate Monitors

    o    LaserHawk®

 

·         Software

    o    RegPerfect

 

Environnment S.A calls ambient monitoring “Air Quality” and splits this segment as follows:

 

Gas analyzers (SO2, H2S, TRS, NO, NO2, NOx, NH3, CO, CO2, O3, THC, BTX, VOC)

Open path multigas D.O.A.S. system

Particulates samplers and analyzers (TSP, PM10, PM2.5, PM1)

Calibration devices

Data acquisition and data management softwares

 

Another category is Emission Monitoring split in the following manner:

 

Multi-gas stationary monitoring systems (extractive IR GFC, in situ IR GFC, FTIR, FID)

Dilution-based stationary monitoring systems

Stack flow meter

Portable or transportable monitoring systems

Particulate monitors

Long-term dioxin and furan sampling system

Data acquisition and data management softwares.

 

Wikipedia did not have much assistance in classification but they did have some information on measurement principles. Gas analyzers employ various techniques to accurately measure concentrations. Some commonly used techniques include: infrared and ultraviolet adsorption, chemiluminescence, fluorescence and beta ray absorption

 

The EPA technology transfer network has various papers which lead one to separate

predictive emissions monitors (PEMS) and CEMS. They single out hazardous air pollution control (HAP) CEMS, fabric filter bag leak detectors, ammonia CEMS, mercury, and PM (particulate).

 

Ron Jernigan has provided regular papers analyzing the experience with CEMs by the utility industry. The reporting segmentation is as follows:

 

Acquisition Method

1. Dilution extractive

2. Extractive

3. In situ

 

Principles of operation

1. SO2 Monitors

        A. Fluorescence

        B. UV Spectrographic

 

2. NOx monitors

        A. Chemiluminescence

        B. UV spectrophotometric

 

3. CO2

        A. IR (Infra Red)

 

4. O2

        A. Paramagnetic

        B. Electrocatalytic

 

A Number of Genetic Lineages Can Be Created from the Above Data

 

Using decisive classification rather than theoretical the practice is not to make a big distinction between single gas and multi gas analyzers. Therefore the genetic lineage by gas type could be:

 

Source Gas Analyzers by Pollutant for Power Plants

 

Genetic Base Class

Aliases

Cousins

CO

 

 

CO2

 

 

Direct Methane

 

 

H2S

 

 

HCl

 

 

Multi gas

 

FTIR multi gas,  NDIR multi gas

NH3

 

 

NOx

 

NO,NO2

SO2

 

 

*THC

Total hydrocarbon

 

*TRS

 

 

 

*For non-utility applications these two pollutants plus O3, BTX, VOC and other pollutants may be continuously analyzed.

 

There is a genetic lineage for Monitoring Acquisition Method, which is shown in Figure 1.

 

There is also a genetic lineage by Principle of Operation, which is shown in Figure 2.

 

Here is one final example to integrate the foster and genetic family. The following shows the most popular SO2 CEM for power plants.

 

Electric Utilities -coal-fired boilers – air quality - FGD

 

Optimization & Instrumentation

Gas Monitoring

CEMS

SO2 - Dilution Extractive

 

--fluorescence -- sources

 

In this case there is a lack of clarity relative to the principle of operation. There needs to be some input and consensus from the industry as to how to clearly classify the principles based on actual use not theory. Once there is consensus in English it will be a much simpler task to prepare the Chinese equivalent.

 

We invite the subscribers to this newsletter to weigh in on any aspect of this endeavor.

 

 

 

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