The use of FGD-gypsum as material for selenium removal from re-circulated waters at a coal-fired power plant equipped with a wet limestone flue gas desulphurisation (FGD) system with use of an Al-additive (to boost the desulphurisation efficiency), has been evaluated by adsorption studies. Potentiometic titration experiments for FGD-gypsum samples, based on the point zero of aqero change (pHpzc) and the potenciometric curves indicate that at pH lower than 7.5 the FGD-gypsum surface is positively charged. This points out that the adsorption of Se in the FGD-gypsum is governed by the protonation of th FGD-gypsum surface. The protonation fo the FGD-gypsum may be attributed to the use of the Al-additive. Click Here For Complete Article Text
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